姓 名:田仕凯 教授 博导 电 话: 0551-63600871 电子邮件: tiansk@ustc.edu.cn 传 真: 主页: | ||
个人简历 | ||
1989.09 - 1993.07, 兰州大学化学系,有机化学,理学学士 1993.09 - 1996.07, 中国科学院上海有机化学研究所,有机合成,理学硕士 1996.09 - 1998.12, 中国科学院上海有机化学研究所,有机合成,理学博士 1999.02 - 2002.04, 美国Brandeis大学化学系,不对称催化,博士后 2002.04 - 2005.08, 美国Vertex制药公司,药物化学,研究员 2005.09 - 现在, 中国科学技术大学化学系,有机化学,教授 | ||
主要研究方向 | ||
有机合成 | ||
文章及专著 | ||
1. Man-Bo Li, Yong Wang, and Shi-Kai Tian*, Regioselective and Stereospecific Cross-Coupling of Primary Allylic Amines with Boronic Acids and Boronates through Palladium-Catalyzed C-N Bond Cleavage, Angew. Chem., Int. Ed. 2012, 51, 2968-2971. 2. Fu-Lai Yang, Xian-Tao Ma, and Shi-Kai Tian*, Oxidative Mizoroki-Heck-Type Reaction of Arylsulfonyl Hydrazides for a Highly Regio- and Stereoselective Synthesis of Polysubstituted Alkenes, Chem. Eur. J. 2012, 18, 1582-1585. 3. Xue-Song Wu and Shi-Kai Tian*, Catalytic Asymmetric Cleavage of sp3 C-N Bonds for Access to Highly Enantioenriched N-Benzylic Sulfonamides, Chem. Commun. 2012, 48, 898-900. 4. Dao-Juan Cheng, Hai-Bian Wu, and Shi-Kai Tian*, Catalytic Asymmetric Pictet-Spengler-Type Reaction for the Synthesis of Optically Active Indolo[3,4-cd][1]benzazepines, Org. Lett. 2011, 13, 5636-5639. 5. Cui-Feng Yang, Jian-Yong Wang, and Shi-Kai Tian*, Catalytic Decarboxylative Alkylation of β-Keto Acids with Sulfonamides via the Cleavage of Carbon-Nitrogen and Carbon?Carbon Bonds, Chem. Commun. 2011, 47, 8343-8345. 6. De-Jun Dong, Yuan Li, Jie-Qi Wang, and Shi-Kai Tian*, Tunable Stereoselective Alkene Synthesis by Treatment of Activated Imines with Nonstabilized Phosphonium Ylides, Chem. Commun. 2011, 47, 2158-2160. 7. Cong-Rong Liu, Fu-Lai Yang, Yi-Zhou Jin, Xian-Tao Ma, Dao-Juan Cheng, Nan Li, and Shi-Kai Tian*, Catalytic Regioselective Synthesis of Structurally Diverse Indene Derivatives from N-Benzylic Sulfonamides and Disubstituted Alkynes, Org. Lett. 2010, 12, 3832-3835. 8. Bai-Ling Yang and Shi-Kai Tian*, Catalytic Coupling of N-Benzylic Sulfonamides with Silylated Nucleophiles at Room Temperature, Chem. Commun. 2010, 46, 6180-6182. 9. De-Jun Dong, Hai-Hua Li, and Shi-Kai Tian*, A Highly Tunable Stereoselective Olefination of Semistabilized Triphenylphosphonium Ylides with N-Sulfonyl Imines, J. Am. Chem. Soc. 2010, 132, 5018-5020. 10. Bai-Ling Yang, Zhen-Tao Weng, Si-Jie Yang, and Shi-Kai Tian*, Byproduct-Catalyzed Four-Component Reactions of Aldehydes with Hexamethyldisilazane, Chloroformates,and Nucleophiles in Acetonitrile Leading to Protected Primary Amines, α-Amino Esters, and β-Amino Ketones, Chem. Eur. J. 2010, 16, 718-723. |